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(R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide

metamifop

CAS: 256412-89-2

Molecular Formula: C23H18ClFN2O4

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(R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide - Names and Identifiers

Name metamifop
Synonyms metamifop
Metamifop [iso]
2-[4-[(6-Chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-MethylpropanaMide
(2R)-2-[4-[(6-chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-methylpropanamide
2-{4-[(5-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy}-N-(2-fluorophenyl)-N-methylpropanamide
(R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide
(2R)-2-{4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy}-N-(2-fluorophenyl)-N-methylpropanamide
MetaMifop((2R)-2-[4-[(6-Chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-MethylpropanaMide
CAS 256412-89-2
InChI InChI=1/C23H18ClFN2O4/c1-14(22(28)27(2)20-6-4-3-5-18(20)25)29-16-8-10-17(11-9-16)30-23-26-19-12-7-15(24)13-21(19)31-23/h3-14H,1-2H3/t14-/m1/s1

(R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide - Physico-chemical Properties

Molecular FormulaC23H18ClFN2O4
Molar Mass440.85
Density1.363±0.06 g/cm3(Predicted)
Melting Point77-81℃
Boling Point589.6±60.0 °C(Predicted)
Flash Point310.373°C
Solubility Soluble in methanol, chloroform and dimethyl sulfoxide.
Vapor Presure0mmHg at 25°C
pKa0.16±0.50(Predicted)
Storage Condition2-8°C
Refractive Index1.634
MDLMFCD22577272

(R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide - Risk and Safety

Risk CodesR20 - Harmful by inhalation
R43 - May cause sensitization by skin contact
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
Safety DescriptionS36/37 - Wear suitable protective clothing and gloves.
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
Hazard Class9

(R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide - Reference

Reference
Show more
1. Peng Qian. The role of barnyard grass glutathione S-transferase in resistance to oxazolamide metabolism [D]. Huazhong Agricultural University, 2020.

(R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide - Reference Information

brief introduction oxazolomide, a herbicide in rice direct seeding fields, has been very popular in rice planting areas in recent years. with the increase of resistance to herbicides such as pentafluoresomethamine, it is becoming more and more difficult to control weeds in rice direct seeding fields. oxazolomide is good for barnyard grass and beef tendon grass equivalent fruits, especially for resistant barnyard grass.
Mechanism of Action Oxazolamide is an aryloxyphenoxy acid ester (AOPP) herbicide, which can inhibit acetyl-CoA carboxylase (ACC enzyme) and promote plant fatty acid synthesis. It is used as a kind of acetyl-CoA carboxylase inhibitor for the treatment of rice field stems and leaves to control various gramineous weeds such as crabgrass, barnyard grass, and gold. The drug is absorbed by the stems and leaves, and is conducted to the growth point through the vascular bundle to achieve the herbicidal effect.
control object oxazolyl oxazolamide has a wider weeding spectrum compared with paddy herbicides such as cyfluoxalate, pentafluoresulam, and bisoxalate, and has a good control effect on most of the paddy fields.
safety field observation results showed that the seedlings with 10% oxazolamide active ingredient content of 120g/hm 2 treatment, 150g/hm 2 treatment, 180g/hm 2 treatment and
300g/hm 2
treatment all showed yellowing phenomenon, and with the increase of dosage, yellow falling has an aggravating trend. The growth of seedlings treated with large dosage is slightly stagnant, but it can be restored in the later period, and has no obvious effect on rice yield.
Last Update:2024-04-09 19:05:11
(R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide
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View History
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